Beilstein J. Org. Chem.2015,11, 1332–1339, doi:10.3762/bjoc.11.143
may possess further functionalities in addition to the phosphorus center such as the γ-hydroxypropyl group which results from the ring opening and π-donor moieties such as aryl, allyl, propargyl and allene which originates from the Grignard reagent.
Keywords: chirogenicphosphorus; Grignard reagents
). Thus, oxaphospholanes can potentially form a new P–C bond in an entirely regioselective manner via cleavage of the single endocyclic P–O bond [35][36][37]. Based on this mechanism, the unique properties of oxaphosphorinanes and oxaphospholanes may also be used to form chirogenic (±)-phosphorus
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Graphical Abstract
Figure 1:
Chemical structures of 2-methoxy-1,3,2-dioxaphospholane 2-oxide (1), 2-ethoxy-1,3,2-dioxaphospholan...